Standard Practice for Preparation of Dried Paint Samples by Hotplate or Microwave Digestion for Subsequent Lead Analysis

SIGNIFICANCE AND USE
5.1 Paint in buildings and related structures needs to be monitored for lead content in order to determine the potential lead hazard. Hence, effective and efficient methods are required for the preparation of paint samples that may contain lead.  
5.2 This practice may be used for the digestion of paint samples that are collected during various lead-hazard control and risk assessment activities associated with lead abatement in and around buildings and related structures. This practice is also suitable for the digestion of paint samples collected from locations such as commercial buildings.  
5.3 This practice may be used to prepare samples that have been obtained in order to ensure compliance with laws that govern lead content in paints.  
5.4 This practice may be used to prepare samples that have been collected for risk assessment purposes.  
5.5 This practice is intended for use with paint samples that are prepared for subsequent analysis by quantitative analytical methods.
SCOPE
1.1 This practice covers the sample preparation procedures for paint samples that are collected during the assessment, management or control of lead hazards.  
1.2 This practice describes the digestion procedures using a hot plate or microwave oven or apparatus for paint samples that are to be analyzed for lead content.  
1.3 This practice covers the general considerations for quantitative sample extraction for total recoverable lead in dried paint samples (either bulk paint or paint powder) using hot plate or microwave heating techniques, or both.  
1.4 This practice contains notes that are explanatory and not part of the mandatory requirements of the standard.  
1.5 This practice is based on NIOSH Methods 7082 and 7105, and on an EPA standard operating procedure for lead in paint.  
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 6.1.2, 6.1.2.1, 6.1.2.2, 6.3.2.4, 8.2.1, and 8.2.2.  
1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Publication Date
31-Aug-2021
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: E1645 − 21
Standard Practice for
Preparation of Dried Paint Samples by Hotplate or
1
Microwave Digestion for Subsequent Lead Analysis
This standard is issued under the fixed designation E1645; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 2. Referenced Documents
2
2.1 ASTM Standards:
1.1 This practice covers the sample preparation procedures
D1129 Terminology Relating to Water
for paint samples that are collected during the assessment,
D1193 Specification for Reagent Water
management or control of lead hazards.
D1356 Terminology Relating to Sampling and Analysis of
1.2 This practice describes the digestion procedures using a
Atmospheres
hotplateormicrowaveovenorapparatusforpaintsamplesthat
E288 Specification for Laboratory Glass Volumetric Flasks
are to be analyzed for lead content.
E969 Specification for Glass Volumetric (Transfer) Pipets
E1605 Terminology Relating to Lead in Buildings
1.3 This practice covers the general considerations for
E1729 Practice for Field Collection of Dried Paint Samples
quantitative sample extraction for total recoverable lead in
for Subsequent Lead Determination
dried paint samples (either bulk paint or paint powder) using
3
hot plate or microwave heating techniques, or both. 2.2 ISO Documents:
ISO Guide 30 Reference materials — Selected terms and
1.4 This practice contains notes that are explanatory and not
definitions
part of the mandatory requirements of the standard.
ISO 1042 Laboratory glassware — One-mark volumetric
1.5 This practice is based on NIOSH Methods 7082 and flasks
ISO 8655 Piston-operated volumetric apparatus — Part 1:
7105, and on an EPA standard operating procedure for lead in
paint. Terminology, general requirements and user recommen-
dations
1.6 The values stated in SI units are to be regarded as
2.3 Other Documents:
standard. No other units of measurement are included in this
NTIS No. PB92–114172 Standard Operating Procedures for
standard.
Lead in Paint by Hotplate- or Microwave-based Acid
1.7 This standard does not purport to address all of the
DigestionsandAtomicAbsorptionorInductivelyCoupled
4
safety concerns, if any, associated with its use. It is the
Plasma Emission Spectrometry
responsibility of the user of this standard to establish appro-
NMAM 7082 and 7105 NIOSH Manual of Analytical
5
priate safety, health, and environmental practices and deter-
Methods, 4th ed.
mine the applicability of regulatory limitations prior to use.
For specific warning statements, see 6.1.2, 6.1.2.1, 6.1.2.2, 3. Terminology
6.3.2.4, 8.2.1, and 8.2.2.
3.1 Definitions—For definitions of terms relating to the
1.8 This international standard was developed in accor-
preparation of dried paint samples that are not given here, refer
dance with internationally recognized principles on standard-
ization established in the Decision on Principles for the
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Development of International Standards, Guides and Recom-
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
mendations issued by the World Trade Organization Technical
Standards volume information, refer to the standard’s Document Summary page on
Barriers to Trade (TBT) Committee.
the ASTM website.
3
Available from International Organization for Standardization (ISO), ISO
Central Secretariat, BIBC II, Chemin de Blandonnet 8, CP 401, 1214 Vernier,
Geneva, Switzerland, http://www.iso.org.
1 4
This practice is under the jurisdiction ofASTM Committee D22 on Air Quality U.S. EPA, Research Triangle Park, NC (1991). Available from National
and is the direct responsibility of Subcommittee D22.12 on Sampling and Analysis Technical Information Service (NTIS), 5301 Shawnee Rd., Alexandria, VA 22312,
of Lead for Exposure and Risk Assessment. http://www.ntis.gov.
5
Current edition approved Sept. 1, 2021. Published October 2021. Originally P.M.Eller,andM.E.Cassinelli,Eds.,NationalInstituteforOccupationalSafety
approved in 1994. Last previous edition approved in 2020 as E1645 – 20a. DOI: & Health, Cincinnati, OH (1994). Available from NIOSH Publications, 1150
10.1520/E1645-21. Tusculum Ave, Cincinnati, OH 45226, Mail Stop C14, http://www.cdc.gov/niosh.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E1645 − 21
to Terminologies D1129, D1356,or E1
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: E1645 − 20a E1645 − 21
Standard Practice for
Preparation of Dried Paint Samples by Hotplate or
1
Microwave Digestion for Subsequent Lead Analysis
This standard is issued under the fixed designation E1645; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This practice covers the sample preparation procedures for paint samples that are collected during the assessment, management
or control of lead hazards.
1.2 This practice describes the digestion procedures using a hot plate or microwave oven or apparatus for paint samples that are
to be analyzed for lead content.
1.3 This practice covers the general considerations for quantitative sample extraction for total recoverable lead in dried paint
samples (either bulk paint or paint powder) using hot plate or microwave heating techniques, or both.
1.4 This practice contains notes that are explanatory and not part of the mandatory requirements of the standard.
1.5 This practice is based on NIOSH Methods 7082 and 7105, and on an EPA standard operating procedure for lead in paint.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of
regulatory limitations prior to use. For specific warning statements, see 6.1.2, 6.1.2.1, 6.1.2.2, 6.3.2.4, 7.2.18.2.1, and 7.2.28.2.2.
1.8 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D1129 Terminology Relating to Water
D1193 Specification for Reagent Water
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
E288 Specification for Laboratory Glass Volumetric Flasks
1
This practice is under the jurisdiction of ASTM Committee D22 on Air Quality and is the direct responsibility of Subcommittee D22.12 on Sampling and Analysis of
Lead for Exposure and Risk Assessment.
Current edition approved Nov. 1, 2020Sept. 1, 2021. Published December 2020October 2021. Originally approved in 1994. Last previous edition approved in 2020 as
E1645 – 20.E1645 – 20a. DOI: 10.1520/E1645-20A.10.1520/E1645-21.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E1645 − 21
E969 Specification for Glass Volumetric (Transfer) Pipets
E1605 Terminology Relating to Lead in Buildings
E1729 Practice for Field Collection of Dried Paint Samples for Subsequent Lead Determination
3
2.2 ISO Documents:
ISO Guide 30 Reference materials — Selected terms and definitions
ISO 1042 Laboratory glassware — One-mark volumetric flasks
ISO 8655 Piston-operated volumetric apparatus — Part 1: Terminology, general requirements and user recommendations
2.3 Other Documents:
NTIS No. PB92–114172 Standard Operating Procedures for Lead in Paint by Hotplate- or Microwave-based Acid Digestions
4
and Atomic Absorption or Inductively Coupled Plasma Emission Spectrometry
5
NMAM 7082 and 7105 NIOSH Manual of Analytical Methods, 4th ed.
3. Terminology
3.1 Definitions—For definitions of terms relating to the preparation of dried paint samples that are not given here, refer to
Terminologies D1129, D1356, or E1605.
3.1.1 batch, n—a group of field or quality control samples that are processed together using the same reagents and equipment.
3.1.2 digestate, n—an acidified aqueous solution that results from digestion of the sample.
3.1.3 digestion, n—the sample preparation process that solubilizes (extracts) targeted analytes present in the sample, and results
in an acidified aqueous solutio
...

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